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Journal of Physical and Chemical Reference Data -- December 2003 -- Volume 32, Issue 4, pp. 1535-1544

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Ultrasonic Parameters as a Function of Absolute Hydrostatic Pressure. II. Mathematical Models of the Speed of Sound in Organic Liquids

Barbara Oakley and Darrin Hanna
School of Engineering and Computer Science, Oakland University, Rochester, Michigan 48309
Meir Shillor
Department of Mathematics and Statistics, Oakland University, Rochester, Michigan 48309
Gary Barber
School of Engineering and Computer Science, Oakland University, Rochester, Michigan 48309

(Received 27 November 2002; revised 17 December 2002; accepted 28 December 2002; published online 9 September 2003)

Polynomial expressions for the speed of sound as a function of pressure for 68 different organic liquids are presented in tabular form. (The liquids form a subset of those discussed in the companion paper: Ultrasonic parameters as a function of absolute hydrostatic pressure. I. A review of the data for organic liquids.) The polynomial expressions are based upon the experimental results reported by many different researchers. For some common liquids, such as benzene, hexane, ethanol, and carbon tetrachloride, the results of as many as five different researchers are reported. These results sometimes vary widely—far more than would be expected from calculated experimental uncertainties. An analysis is presented of how well pressure-dependent polynomials fit the experimental data when the number of coefficients is increased. The error in the polynomial fit is also explored when both pressure and temperature dependencies are present. Finally, differences between ultrasonic and Brillouin scattering experimental results are discussed. ©2003 American Institute of Physics.


doi:10.1063/1.1555589
PACS: 43.20.Hq, 43.35.Bf, 43.35.Cg        Additional Information


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